Surfaces can be altered for use in Boolean operations or for exportation to a CAD package.
The prompt line provides feedback on the result of the operation. For example: “Created 2 shells with 0 boundaries (0 non-manifold).”
If some boundaries are left open, small red arrows point to them.
Depending on how you set the options, a shell may not match the original surfaces exactly. In this case, unstitching will not produce surfaces that match the originals exactly either.
See Align curves and surfaces with continuity
If you stitch an object, then scale it, then unstitch it, you may not be able to re-stitch the object. This is because the scaling operation can increase the gaps between surfaces beyond the current tolerances.