In this lesson, you set the scene for late-day illumination, and adjust the exposure accordingly.
Set up the lesson:
Change the time of day to late afternoon:
Time group, set the Hours to 18 and Mins. (Minutes) to 30 (6:30 PM, or 1830 hours). 
The scene is fairly dim, but you can improve this by adjusting the exposure to a setting more appropriate for this time of day.
Exposure group, Shutter Speed is set to a proper exposure for a camera angle facing the sun. But you can increase the amount of light entering the scene by adjusting the camera lens aperture. 
The overall illumination is much improved, although the outline of the sun disc is lost.
Create a sunset exposure:
Here, you will adjust scene exposure so that objects are convincingly illuminated by the setting sun.
Control Parameters rollout
Time group, set the Hours to 19 and the Mins. (Minutes) to 40 (7:40 PM, or 1940 hours). 
The scene is extremely dark because the exposure is still set for an earlier time of day.

The “mr Physical Sky shader” produces a vivid sky gradient, and details around the pool are much more apparent.
Save your work:
You can create a Daylight system to simulate real-world outdoor lighting conditions at any time of day, at any location on the planet. mental ray offers a range of presets that define proper exposure settings for specific lighting conditions, which you can adjust manually as needed. You can also add Sky Portal objects to channel sky light into doorways and windows of structures, to enhance their interior illumination.