When you insert a corner window, you can change the opening width measure from the Properties palette to:  
-  Inside of Opening. Measure the corner window from one wall end to the inside (shorter side) of the wall corner. 
 
-  Outside of Opening. Measure the corner window from one wall end to the outside (longer side) of the wall corner. 
 
-  Center of Opening. Measure the corner window from one wall end to the intersection of both walls at the wall corner.