After placing mullions on a curtain wall, you can change the material for all mullions of that type. 
-  In the drawing area, select a mullion. 
- On the Properties palette, click Edit Type. 
- Select a mullion material from Materials and Finishes. 
  You can create a new mullion material if one does not exist. 
   
- Click OK. 
  Note: Changing the material for a mullion family type changes the material for all mullions of that type. If the material changes affect the mullions on only one curtain wall, create and apply a new mullion family type.